• Resirkulasjon
  • Råmetanol
  • Syntesegass
  • Inn på reaktor
  • Ut av reaktor
  • Purge
  • Ntnu fakultet for kjemi og biologi Norges teknisk-naturvitenskapelige Institutt for kjemisk prosessteknologi universitet




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    Purge














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    6.3 %

    47.1

    2071.7

    5.78%

    53.5

    2353.1

    CO

    3.1 %

    23.2

    648.8

    3.10%

    28.6

    802.1

    H2

    68.3 %

    510.3

    1030.9

    72.18%

    667.6

    1348.6

    CH4

    17.0 %

    127.0

    2038.7

    15.19%

    140.5

    2255.4

    N2

    3.2 %

    23.9

    670.0

    2.20%

    20.4

    570.6

    Ar

    1.9 %

    14.2

    567.2

    1.12%

    10.3

    413.4

    H2O

    0.02%

    0.1

    2.7

    0.01%

    0.1

    2.4

    CH3OH

    0.18%

    1.3

    43.1

    0.42%

    3.9

    124.8







    747.2

    7073.0




    925.0

    7870.4

























    F11
    1. Resirkulasjon














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    6.3 %

    2444.3

    107572.5

    5.78%

    2311.3

    101718.4

    CO

    3.1 %

    1202.7

    33688.7

    3.10%

    1237.8

    34671.1

    H2

    68.3 %

    26499.0

    53528.0

    72.18%

    28860.3

    58297.8

    CH4

    17.0 %

    6595.7

    105860.3

    15.19%

    6074.4

    97494.0

    N2

    3.2 %

    1241.5

    34787.8

    2.20%

    880.3

    24666.9

    Ar

    1.9 %

    737.2

    29449.6

    1.12%

    447.3

    17871.3

    H2O

    0.02%

    7.8

    139.8

    0.01%

    5.8

    105.2

    CH3OH

    0.18%

    69.8

    2237.6

    0.42%

    168.3

    5393.8







    38798.0

    367264.4




    39985.6

    340218.4

























    F13
    1. Råmetanol














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    1.2 %

    49.3

    2171.1

    1.91%

    76.9

    3383.8

    CO

    0.1 %

    2.5

    69.1

    0.03%

    1.1

    31.1

    H2

    0.7 %

    28.8

    58.1

    0.43%

    17.5

    35.3

    CH4

    0.6 %

    24.7

    395.9

    0.40%

    16.1

    258.6

    N2

    0.04%

    1.6

    46.1

    0.05%

    2.0

    56.4

    Ar

    0.04%

    1.6

    65.7

    0.02%

    0.8

    33.5

    H2O

    20.4 %

    838.6

    15112.4

    19.82%

    799.1

    14399.7

    CH3OH

    76.8 %

    3157.2

    101158.2

    77.34%

    3117.5

    99885.1







    4111.0

    119076.6




    4031.0

    118083.4


    Tabell B7.4: Sammenligning mellom bruk av omsetningsreaktor og likevektsreaktor i Hysys.




    HYSYS, omsetningsreaktor

    HYSYS, likevektsreaktor

























    F1
    1. Syntesegass














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    8.2%

    918.4

    40418.8

    8.2%

    918.4

    40418.8

    CO

    21.1%

    2363.2

    66193.2

    21.1%

    2363.2

    66193.2

    H2

    68.9%

    7716.8

    15587.9

    68.9%

    7716.8

    15587.9

    CH4

    1.4%

    156.8

    2516.6

    1.4%

    156.8

    2516.6

    N2

    0.2%

    22.4

    627.6

    0.2%

    22.4

    627.6

    Ar

    0.1%

    11.2

    447.4

    0.1%

    11.2

    447.4

    H2O

    0.1%

    11.2

    201.8

    0.1%

    11.2

    201.8

    CH3OH

    0.0%

    0

    0.0

    0.0%

    0

    0.0




    100.0%

    11200

    125993.5

    100.0%

    11200

    125993.5

























    F4
    1. Inn på reaktor














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    6.31%

    3229.7

    142137.2

    6.38%

    2923.4

    128661.0

    CO

    7.04%

    3601.0

    100864.3

    6.99%

    3204.6

    89760.7

    H2

    71.46%

    36577.1

    73885.7

    71.52%

    32768.1

    66191.6

    CH4

    12.17%

    6231.2

    100010.6

    12.11%

    5547.9

    89043.7

    N2

    1.76%

    902.7

    25294.5

    1.75%

    804.1

    22530.4

    Ar

    0.90%

    458.5

    18318.7

    0.89%

    408.6

    16322.3

    H2O

    0.03%

    17.0

    307.1

    0.04%

    16.2

    292.6

    CH3OH

    0.33%

    168.3

    5393.8

    0.32%

    145.9

    4673.9







    51185.6

    466211.9




    45818.8

    417476.2

























    F5
    1. Ut av reaktor














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    5.43%

    2441.6

    107455.7

    5.40%

    2134.5

    93937.4

    CO

    2.82%

    1267.6

    35504.2

    2.18%

    864.1

    24204.7

    H2

    65.74%

    29546.1

    59683.1

    65.02%

    25720.3

    51954.9

    CH4

    13.86%

    6231.2

    100010.6

    14.02%

    5547.9

    89043.7

    N2

    2.01%

    902.7

    25294.5

    2.03%

    804.1

    22530.4

    Ar

    1.02%

    458.5

    18318.7

    1.03%

    408.6

    16322.3

    H2O

    1.79%

    805.1

    14507.5

    2.04%

    805.2

    14510.2

    CH3OH

    7.32%

    3289.8

    105406.4

    8.28%

    3275.3

    104941.3







    44942.6

    466180.7




    39559.9

    417444.9

























    F10
    1. Purge














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    5.78%

    53.5

    2353.1

    5.79%

    52.1

    2294.1

    CO

    3.10%

    28.6

    802.1

    2.43%

    21.9

    612.7

    H2

    72.18%

    667.6

    1348.6

    72.36%

    651.3

    1315.6

    CH4

    15.19%

    140.5

    2255.4

    15.57%

    140.2

    2249.5

    N2

    2.20%

    20.4

    570.6

    2.26%

    20.3

    569.4

    Ar

    1.12%

    10.3

    413.4

    1.15%

    10.3

    412.7

    H2O

    0.01%

    0.1

    2.4

    0.01%

    0.1

    2.4

    CH3OH

    0.42%

    3.9

    124.8

    0.42%

    3.8

    121.5







    925.0

    7870.4




    900.0

    7577.8

























    F11
    1. Resirkulasjon














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    5.78%

    2311.3

    101718.4

    5.79%

    2005.0

    88242.2

    CO

    3.10%

    1237.8

    34671.1

    2.43%

    841.4

    23567.5

    H2

    72.18%

    28860.3

    58297.8

    72.36%

    25051.3

    50603.7

    CH4

    15.19%

    6074.4

    97494.0

    15.57%

    5391.1

    86527.0

    N2

    2.20%

    880.3

    24666.9

    2.26%

    781.7

    21902.8

    Ar

    1.12%

    447.3

    17871.3

    1.15%

    397.4

    15874.8

    H2O

    0.01%

    5.8

    105.2

    0.01%

    5.0

    90.7

    CH3OH

    0.42%

    168.3

    5393.8

    0.42%

    145.9

    4673.9







    39985.6

    340218.4




    34618.8

    291482.7

























    F13
    1. Råmetanol














    Fraksjon

    kmol/h

    kg/h

    Fraksjon

    kmol/h

    kg/h

    CO2

    1.91%

    76.9

    3383.8

    1.91%

    77.3

    3401.2

    CO

    0.03%

    1.1

    31.1

    0.02%

    0.9

    24.5

    H2

    0.43%

    17.5

    35.3

    0.43%

    17.6

    35.5

    CH4

    0.40%

    16.1

    258.6

    0.41%

    16.6

    266.1

    N2

    0.05%

    2.0

    56.4

    0.05%

    2.1

    58.0

    Ar

    0.02%

    0.8

    33.5

    0.02%

    0.9

    34.5

    H2O

    19.82%

    799.1

    14399.7

    19.80%

    800.1

    14417.1

    CH3OH

    77.34%

    3117.5

    99885.1

    77.35%

    3125.7

    100145.8







    4031.0

    118083.4




    4040.9

    118382.7

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